Zendesk does this and seems a nice safety feature. Here is a sample email from them:
This is an automated message from Zendesk to keep you informed of major
changes made to your settings.
A new admin user has been added to your account by Andrew Ardron (aca@prospectsoft.com).
Name: Dan Bryant
Email: djb@prospectsoft.com
Please contact your account's administrator if you think this message is mistaken.
This email is a service from ProspectSoft. Delivered by Zendesk